This study assessed measures operationalizing concepts in relational turbulence theory (Solomon, Knobloch, Theiss, & McLaren, 2016). Studies of relational turbulence in marriage have used measures developed in research on dating couples; therefore, one goal was evaluating these variables in a general population sample of married individuals (N = 1,469). A second goal addressed problems in measures of relational uncertainty by assessing alternative scales. Third, associations between relational turbulence theory variables and measures of cognitive, emotional, and communicative phenomena were estimated. Fourth, the distinctiveness of relational turbulence measures relative to measures of other relational qualities was assessed. The conclusions advance new, Likert relational uncertainty scales and highlight the validity of relational turbulence constructs as distinctive predictors of cognitions, emotions, and communication.