This study developed and tested a structural model that examined the relationships among parents’ work–family conflict, frustration, non‐supportive parenting behaviors, and children's work centrality. Data were collected from a sample that included undergraduates and their parents. Results of structural equation modeling analyses supported a spillover effect of paternal and maternal work–family conflict on their frustration. Findings also showed that paternal frustration was significantly related to non‐supportive paternal parenting behaviors. However, maternal frustration was not significantly related to non‐supportive maternal parenting behavior. Paternal non‐supportive parenting behavior was significantly and negatively associated with children's work centrality while maternal non‐supportive parenting behavior was not. Implications of the findings are discussed.