This study explores the relationships between career and psychosocial mentoring, and the employee outcomes of affective organizational commitment (AOC), job involvement, and turnover intention. The relationships between psychosocial mentoring and the employee outcomes of AOC and turnover intention were significant. Building from affective events theory, the authors found that AOC mediated the relationship between psychosocial mentoring and employee turnover intention. The study emphasizes the importance of emotion and affect by showing that employees who experienced positive mentoring events at work exhibited higher levels of AOC, which in turn led to reduced turnover intention. The implications are discussed.