Multivariate psychological processes have recently been studied, visualized, and analyzed as networks. In this network approach, psychological constructs are represented as complex systems of interacting components. In addition to insightful visualization of dynamics, a network perspective leads to a new way of thinking about the nature of psychological phenomena by offering new tools for studying dynamical processes in psychology. In this article, we explain the rationale of the network approach, the associated methods and visualization, and illustrate it using an empirical example focusing on the relation between the daily fluctuations of emotions and neuroticism. The results suggest that individuals with high levels of neuroticism had a denser emotion network compared with their less neurotic peers. This effect is especially pronounced for the negative emotion network, which is in line with previous studies that found a denser network in depressed subjects than in healthy subjects. In sum, we show how the network approach may offer new tools for studying dynamical processes in psychology.