Informal marital separation often quickly leads to divorce, but can become long-lasting, especially among disadvantaged populations. In this study, we focus on the timing of divorce after separating and examine how unemployment before or during separation affects this pivotal moment in the divorce process. Using data from the National Longitudinal Survey of Youth, 1979 Cohort (N = 2,219), we track unemployment before and during separation and show that men’s unemployment during separation, rather than women’s, reduces the likelihood of divorce, independent of preseparation unemployment and other characteristics. For men, unemployment during a marital separation prolongs the divorce process, creating an extended period of uncertainty in marital relationships on the brink of dissolution. We discuss the gendered relationship observed between employment status during an informal separation and an estranged couple’s decision to complete the divorce process.