In this investigation, the attention is focused on the minimum bending radii of 2196-T8511 and 2099-T83 Al-Li alloy extrusions. To predict the failure of Al-Li alloys, sheet and extrusion stretch bending tests are developed, carried out and simulated using finite element model. The theoretical minimum bending radius is introduced to derive a safe lower limit for the bending radius which can serve as a guideline for tool and product design. Stretch bending tests of Al-Li alloys are performed using the three-point bending test and displacement-controlled stretch bending test at room temperature. The finite element model incorporates three-dimensional solid elements and ductile damage modeling. The experimental results show that Al-Li alloy extrusions in stretch bending show three types of failures, occurring at the unbent region near the entrance of the jaws, at the region below the exit of the die and within the region in contact with the die, respectively. Comparison between predicted values and experimental results has been made, a consistent agreement being achieved, reflecting the reliability of the present model. The three types of failure mechanisms which compete with each other are tensile localization failure, die-corner failure and shear failure, respectively. Based on the analytical models, experiments and simulations, it appears that the three distinct failures need to be applied to predict the minimum bending radius and range of failures that can occur with 2196-T8511 and 2099-T83 Al-Li alloy extrusions in stretch bending.