Entrepreneurship has emerged as an important career option in several developing countries, particularly in Africa. Consequently, entrepreneurship education and training has been sought out by people who have low or no formal education. Governments and donors have tendency to consider entrepreneurship as an instrument to lift up the most vulnerable population such as uneducated women, school drop outers and people with disabilities. However, there is a shortage of technological entrepreneurship in developing countries. This paper investigated the influential factors affecting the entrepreneurial motivation, intentions and decisions among African scientists and engineers’ postgraduates from China universities since 1995 to 2014. Only 6% of respondents are in technological entrepreneurship related to their field of graduation. Conclusion remark is given to encourage technological entrepreneurship which will provide more opportunities, create jobs and improve people’s quality of life.